The Deng Group

2017

66. Sun, Jian; Gao,Yafei; Deng, Liang*. Low-Coordinate NHC-Cobalt(0)-Olefin Complexes: Synthesis, Structure, and Their Reactions with Hydrosilanes. Inorg. Chem., 2017, 56(17), 10775-10784.

65. Mo, Zhenbo; Deng, Liang*. Open-shell iron hydrocarbyls. Coordination Chemistry Reviews, 2017, 350, 280-299.

64. Iannuzzi, Theresa E.; Gao, Yafei; Baker, Tessa M.; Deng, Liang; Neidig, Michael L*. Magnetic circular dichroism and density functional theory studies of electronic structure and bonding in cobalt(II) - N-heterocyclic carbene complexes. Dalton Trans., 2017, 46, 13290-13299.

63. Liu, Yang; Du, Jingzhen; Deng, Liang*. Synthesis, Structure, and Reactivity of Low-Spin Cobalt(II) Imido Complexes [(Me3P)3Co(NAr)]. Inorg. Chem., 2017, 56(14), 8278–8286.

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62. Liu, Jian; Hu, Lianrui; Wang, Lei; Chen, Hui*; Deng, Liang*. An Iron(II) Ylide Complex as a Masked Open-Shell Iron Alkylidene Species in Its Alkylidene-Transfer Reactions with Alkenes. J. Am. Chem. Soc., 2017, 139(10), 3876–3888.

61. Liu, Yang; Deng, Liang*. Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes. J. Am. Chem. Soc., 2017, 139(5), 1798–1801.

60. Sun, Jian; Luo, Lun; Luo, Yi; Deng, Liang*. An NHC-Silyl-NHC Pincer Ligand for the Oxidative Addition of C-H, N-H, and O-H Bonds to Cobalt(I) Complexes. Angew. Chem. Int. Ed., 2017, 56, 2720–2724.

59. Yao, Xiaonan; Du, Jingzhen; Zhang, Yiquan; Leng, Xuebing; Yang, Muwen; Jiang, Shangda; Wang, Zhenxing; Ouyang, Zhongwen; Deng, Liang*; Wang, Bingwu*; Gao, Song*. Two-Coordinate Co(II) Imido Complexes as Outstanding Single-Molecule Magnets. J. Am. Chem. Soc., 2017, 139(1), 373-380. (Y.X. and D.J. contributed equally).

2016

58. Wang, Lijun; Cheng, Jun; Deng, Liang*. A Square Planar Iron(II) Biphenyl-2,2’-diyl Complex with NHC Ligation: Synthesis, Characterization, and its Reactivity toward Unsaturated Organic Substrates. Inorg. Chim. Acta, 2017, 460, 49–54.

57. Ouyang, Zhenwu; Cheng, Jun; Li, Lingling; Bao, Xiaoli, Deng, Liang*. High-Spin Iron(I) and Iron(0) Dinitrogen Complexes Supported by N-Heterocyclic Carbene Ligands. Chem. Eur. J., 2016, 22, 14162–14165.

56. Gao, Yafei; Deng, Liang*. Converting carbon dioxide into alkanes via alkane reverse combustion reaction. Sci. Bull., 2016, 61(15), 1160–1162.

55. Deng, Liang; You, Shuli. Organometallics in Asia. Organometallics, 2016, 35(10), 1341–1342.

54. Ouyang, Zhenwu; Meng, Yinshan; Cheng, Jun; Xiao, Jie; Gao, Song; Deng, Liang*. Three- and Four-Coordinate Homoleptic Iron(I)–NHC Complexes: Synthesis and Characterization. Organometallics, 2016, 35(10), 1361–1367.

53. Liu, Yuesheng; Wang, Lijun; Deng, Liang*. Selective Double Carbomagnesiation of Internal Alkynes Catalyzed by Iron-N-Heterocyclic Carbene Complexes: A Convenient Method to Highly Substituted 1,3-Dienyl Magnesium Reagents. J. Am. Chem. Soc., 2016, 138(1), 112–115.

52. Sun, Jian; Deng, Liang*. Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes. ACS Catal., 2016, 6(1), 290–300.

2015

51. Wang, Lei; Hu, Lianrui; Zhang, Hezhong; Chen, Hui*; Deng, Liang*. Three-Coordinate Iron(IV) Bisimido Complexes with Aminocarbene Ligation: Synthesis, Structure, and Reactivity. J. Am. Chem. Soc., 2015, 137(44), 14196–14207.

50. Meng, Yinshan; Mo, Zhenbo; Wang, Bingwu; Zhang, Yiquan*; Deng, Liang*; Gao, Song*. Observation of the Single-Ion Magnet Behavior of d8 Ions on Two-Coordinate Co(I)-NHC Complexes. Chem. Sci., 2015, 6, 7156-7162.

49. Du, Jingzhen; Wang, Linbo; Xie, Meihua; Deng, Liang*. A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity. Angew. Chem. Int. Ed., 2015, 54, 12640–12644.

48. Liu, Yuesheng; Wang, Lei; Deng, Liang*. Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity. Organometallics, 2015, 34(17), 4401–4407.

47. Ouyang, Zhenwu; Du, Jingzhen; Wang, Lei; Kneebone, Jared L.; Neidig, Michael L.; Deng, Liang*. Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization. Inorg. Chem., 2015, 54(17), 8808–8816.

46. Li, Jiyang; Wang, Dong; Wang, Yuan; Du, Hongbin; Deng, Liang; Hou, Xuelong; Yu, Jihong*. 若干功能体系的定向设计与构筑. 科学通报, 2015, 60, 1987-1991.

45. Wang, Xiaojie; Zhang, Jia; Wang, Lei; Deng, Liang*.High-Spin Iron(II) Alkynyl Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Reactivity Study. Organometallics, 2015, 34(12), 2775–2782.

44. Liu, Yuesheng; Luo, Lun; Xiao, Jie; Wang, Lei; Song, You; Qu, Jingping; Luo, Yi*; Deng, Liang* .Four-Coordinate Iron(II) Diaryl Compounds with Monodentate N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Their Tetrahedral-Square Planar Isomerization in Solution. Inorg. Chem.,2015, 54(10), 4752–4760. (Cover Article)

43. Sun, Jian; Ou, Chong; Wang, Chao*; Uchiyama, Masanobu; Deng, Liang*.Silane-Functionalized N-Heterocyclic Carbene–Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co–Si Bond. Organometallics, 2015, 34(8), 1546–1551.

42. Liu, Yuesheng; Xiao, Jie; Wang, Lei; Song, You; Deng, Liang*.Carbon–Carbon Bond Formation Reactivity of a Four-Coordinate NHC-Supported Iron(II) Phenyl Compound. Organometallics, 2015, 34(3), 599–605.

2014

41. Mo, Zhenbo; Xiao, Jie; Gao, Yafei; Deng, Liang*.Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes. J. Am. Chem. Soc.,2014,136(50), 17414–17417.

40.Zhang, Long; Liu, Yuesheng; Deng, Liang*.Three-Coordinate Cobalt(IV) and Cobalt(V) Imido Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Their Distinct Reactivity in C–H Bond Amination. J. Am. Chem. Soc.,2014,136(44), 15525–15528.

39.Mo, Zhenbo; Ouyang, Zhenwu; Wang, Lei; Fillman, K.; Neidig, M. L.*; Deng, Liang *. Two- and Three-Coordinate Formal Iron(I) Compounds Featuring Monodentate Aminocarbene Ligands. Org. Chem. Front., 2014, 1, 1040-1044.

38. Zhang, Hezhong; Ouyang, Zhenwu; Liu, Yuesheng; Zhang, Qiang; Wang, Lei; Deng, Liang*. (Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents. Angew. Chem. Int. Ed., 2014, 53, 8432 –8436

37. Liu, Yang; Shi, Min*; Deng, Liang*. Iron(II) Dihydrocarbyls Supported by a Biphenyl-Linked Bis(benzimidazol-2-ylidene) Ligand: Syntheses and Characterization. Organometallics, 2014, 33(20), 5660–5669.

36. Mo, Zhenbo; Deng, Liang*. Post-Functionalization: A Useful Method for the Synthesis of Donor-Functionalized N-Heterocyclic Carbene–Transition-Metal Catalysts. Synlett 2014, 25(08), 1045-1049

2013

35. Young Career Focus: Professor Liang Deng (Shanghai Institute of Organic Chemistry, P. R. of China) Synform 2013/10

34. Ouyang, Zhenwu; Deng, Liang*. Iron(II) Complexes Featuring Bidentate N-Heterocyclic Carbene-Silyl Ligands: Synthesis and Characterization. Organometallics 2013, 32(24), 7268-7271

33. Zuo, Wansheng; Zhang, Long; Xie, Meihua*; Deng, Liang*. Square Planar Nickel(II) Complexes with Halogenated o-Diiminobenzosemiquinonato Ligation: Synthesis, Characterization, and Redox Property. Chin. J. Chem. 2013, 31(12), 1473-1482

32. Mo, Zhenbo; Liu, Yang; Deng, Liang*. Anchoring Silyl Donors on N-Heterocyclic Carbene via Cobalt-Mediated Silylation of Benzylic C-H Bond. Angew. Chem. Int. Ed. 2013, 52(41), 10845-10849

31. Zhang, Long; Xiang, Li; Yu, Yihua; Deng, Liang*. Reactivity of a Bis(amidinato)iron(II) Complex [Fe(MesC(NPri)2)2] toward Some Oxidizing Reagents. Inorganic Chemistry 2013, 52(10), 5906-5913

30. Xiao, Jie; Deng,Liang*.Iron-mediated C-H bond amination by organic azides on a tripodal bis(anilido)iminophosphorane platform. Dalton Transactions 2013, 42, 5607-5610

29. Wang, Xiaojie; Mo,Zhenbo; Xiao, Jie; Deng,Liang*. Monomeric Bis(anilido)iron(II) Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Redox Reactivity toward Aryl Halides. Inorganic Chemistry 2013, 52(1), 59-65

2012

28. Mo,Zhenbo; Chen, Dake; Leng, Xuebin; Deng,Liang*.Intramolecular C(sp3)–H Bond Activation Reactions of Low-Valent Cobalt Complexes with Coordination Unsaturation. Organometallics 2012, 31(20), 7040-7043.

27. Mo,Zhenbo; Zhang,Qiang; Deng,Liang*. Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents.Organometallics 2012, 31(18), 6518-6521.

26. Zhang,Long; Deng,Liang*.C-H bond amination by iron-imido/nitrene species. Chinese Science Bulletin 2012, 57(19), 2352-2360.

25. Zhang,Qiang; Xiang, L; Deng,Liang*.Dinuclear Iron–Imido Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Redox Reactivity. Organometallics 2012, 31(12), 4537-4543.

24. Xiao, Jie; Deng, Liang*. Synthesis, Structure, and Reactivity Study of Iron(II) Complexes with Bulky Bis(anilido)thioether Ligation. Organometallics 2012, 31(1), 428-434.

2011

23. Mo, Zhenbo; Li, Yuxue; Lee, Hung Kay; Deng, Liang*. Square-Planar Cobalt Complexes with Monodentate N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Catalytic Application. Organometallics 2011, 30(17), 4687-4694.

22. Xiang, Li; Xiao, Jie; Deng, Liang*. Synthesis, Structure, and Reactivity of Organo-Iron(II) Complexes with N-Heterocyclic Carbene Ligation. Organometallics 2011, 30(7), 2018-2025.

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Before 2011

21. Deng, Liang; Majumdar, Amit; Lo, Wayne; Holm, R. H. Stabilization of 3:1 Site-Differentiated Cubane-Type Clusters in the [Fe4S4]1+ Core Oxidation State by Tertiary Phosphine Ligation: Synthesis, Core Structural Diversity, and S = 1/2 Ground States. Inorganic Chemistry (2010), 49(23), 11118-11126.

20. Qiu, Zaozao; Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei. Synthesis and Structural Characterization of Group 8 Metal-Carboryne Complexes. Organometallics (2010), 29(20), 4541-4547.

19. Chakrabarti, Mrinmoy; Deng, Liang; Holm, R. H.; Munck, Eckard; Bominaar, Emile L. The Modular Nature of All-Ferrous Edge-Bridged Double Cubanes. Inorganic Chemistry (2010), 49(4), 1647-1650.

18. Ren, Shikuo; Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei. Synthesis and Structural Characterization of Zirconium-Carboryne Complexes. Organometallics (2009), 28(19), 5749-5756.

17. Wang, Chao; Deng, Liang; Yan, Jun; Wang, Hailin; Luo, Qian; Zhang, Wen-Xiong; Xi, Zhenfeng. Zirconocene-mediated ligand-switched selective cleavage of active and inert carbon-carbon bonds in allylcyclopropanes. Chemical Communications (2009), (29), 4414-4416.

16. Deng, Liang; Bill, Eckhard; Wieghardt, Karl; Holm, R. H. Cubane-Type Co4S4 Clusters: Synthesis, Redox Series, and Magnetic Ground States. Journal of the American Chemical Society (2009),? 131(31),? 11213-11221.

15. Huang, Deguang; Deng, Liang; Sun, Jibin; Holm, R. H. Cleavage of Ni-(m2-S)-Ni Bridges in Dinuclear Nickel(II) Dithiolate Pincer Complexes and Related Reactions. Inorganic Chemistry (2009), 48(13), 6159-6166.

14. Chakrabarti, Mrinmoy; Deng, Liang; Holm, R. H.; Munck, Eckard; Bominaar, Emile L. Mossbauer, Electron Paramagnetic Resonance, and Theoretical Studies of a Carbene-Based All-Ferrous Fe4S4 Cluster: Electronic Origin and Structural Identification of the Unique Spectroscopic Site. Inorganic Chemistry (2009), 48(7), 2735-2747.

13. Deng, Liang; Holm, R. H. Stabilization of Fully Reduced Iron-Sulfur Clusters by Carbene Ligation: The [FenSn]0 Oxidation Levels (n = 4, 8). Journal of the American Chemical Society (2008), 130(30), 9878-9886.

12. Deng, Liang; Xie, Zuowei. Advances in the chemistry of carboranes and metallacarboranes with more than 12 vertices. Coordination Chemistry Reviews (2007), 251(17-20), 2452-2476.

11. Deng, Liang; Xie, Zuowei. A Journey from 12-Vertex to 14-Vertex Carboranes and to 15-Vertex Metallacarboranes. Organometallics (2007), 26(8), 1832-1845.

10. Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei. Synthesis, Structure, Reactivity, and Thermal Isomerization of Boron-Substituted 13-Vertex Cobaltacarboranes (h5-Cp)Co(h6-R2C2B10Me8H2) (R = H, Et). Inorganic Chemistry (2007), 46(7), 2716-2724.

9. Zhang, Jian; Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei. Role of C,C'-Linkage in the Formation and Stabilization of Supercarboranes. Synthesis and Structure of Carbon-Atoms-Apart 13-Vertex Carborane and 14-Vertex Metallacarborane. Journal of the American Chemical Society (2007), 129(1), 18-19.

8. Deng, Liang; Zhang, Jian; Chan, Hoi-Shan; Xie, Zuowei. Synthesis and structure of 14- and 15-vertex ruthenacarboranes. Angewandte Chemie, International Edition (2006), 45(26), 4309-4313.

7. Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei. Nickel-Mediated Regioselective [2 + 2 + 2] Cycloaddition of Carboryne with Alkynes. Journal of the American Chemical Society (2006), 128(24), 7728-7729.

6. Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei. Synthesis, Structure, and Reactivity of 13-Vertex Carboranes and 14-Vertex Metallacarboranes. Journal of the American Chemical Society (2006), 128(15), 5219-5230.

5. Deng, Liang; Cheung, Mak-Shuen; Chan, Hoi-Shan; Xie, Zuowei. Reduction of 1,2-(CH2)n-1,2-C2B10H10 by Group 1 Metals. Effects of Bridge Length/Rigidity on the Formation of Carborane Anions. Organometallics (2005), 24(25), 6244-6249.

4. Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei. Synthesis, Structure, and Reactivity of a Zirconocene-Carboryne Precursor. Journal of the American Chemical Society (2005), 127(40), 13774-13775.

3. Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei. Synthesis, reactivity, and structural characterization of a 14-vertex carborane. Angewandte Chemie, International Edition (2005), 44(14), 2128-2131.

2. Yu, Tao; Sun, Xiaohua; Wang, Congyang; Deng, Liang; Xi, Zhenfeng. Zirconocene-mediated intermolecular coupling of Si-tethered diynes with alkynes, ketones, aldehydes, and isocyanates by means of novel skeletal rearrangement of zirconacyclobutene-silacyclobutene and zirconacyclohexadiene-silacyclobutene fused-ring intermediates. Chemistry--A European Journal (2005), 11(6), 1895-1902.

1. Yu, Tao; Deng, Liang; Zhao, Changjia; Li, Zhiping; Xi, Zhenfeng. Alkyne and ketone induced novel cleavage of a C-C bond and a C-Si bond in zirconacyclobutene-silacyclobutene fused ring compounds. Tetrahedron Letters (2003), 44(4), 677-679.

©2012 The Deng Research Group